Breakthrough Reduces Harmful Emissions from Hydrogen Engines

Key Takeaways

Enhanced Catalyst Efficiency: Mixing platinum with Y zeolites creates a water-rich environment that boosts hydrogen activation, improving nitrogen oxide (NOx) reduction by 4-5 times.

Broad Application Potential: The technology can benefit not only hydrogen engines but also diesel engines with hydrogen injection systems, making it suitable for trucks, buses, and backup power generators.

Scalable and Practical Solution: With commercialization underway, this low-cost innovation aligns with China’s goals to reduce pollution, offering a practical alternative to diesel engines and supporting the green energy transition.

Visualization of platinum and Y zeolite molecules enhancing catalytic reactions to reduce nitrogen oxide emissions in hydrogen combustion engines.

Hydrogen internal combustion engines (ICEs) are gaining momentum as a low-carbon energy solution. While they promise clean energy by producing no carbon dioxide during combustion, they aren’t entirely pollution-free—they emit nitrogen oxides (NOx), which contribute to air pollution and respiratory issues. Now, scientists have discovered a cost-effective method to slash NOx emissions, improving air quality without compromising engine performance.

The key lies in boosting the catalytic converter’s efficiency using Y zeolites, a highly porous material that significantly enhances the reaction between nitrogen oxides and hydrogen. Infusing platinum catalysts with Y zeolites increases the conversion of NOx into harmless nitrogen gas and water vapor by a factor of four to five at moderate engine temperatures of around 250°C. These results, published in Nature Communications, offer a promising strategy for reducing pollution in hydrogen-powered engines—particularly during cold starts, when engines are still warming up and tend to produce higher emissions.

A Win for Heavy-Duty Vehicles and Diesel Alternatives

What makes this breakthrough especially impactful is its potential beyond passenger cars. Heavy-duty trucks, buses, off-road equipment, and backup generators—all crucial to China’s infrastructure—could benefit from this technology. The team highlights that diesel engines outfitted with hydrogen injection systems could also see significant reductions in NOx emissions. This approach mimics the selective catalytic reduction (SCR) systems commonly used in diesel trucks but leverages hydrogen for even cleaner results.

How Y Zeolites Unlock Cleaner Combustion

Zeolites, a class of low-cost crystalline materials, are composed of silicon, aluminum, and oxygen atoms arranged in a three-dimensional framework with uniform pores. Their structure provides a large surface area and optimized channels that improve catalytic reactions by ensuring pollutants break down efficiently. This makes them ideal for use in hydrogen combustion systems, which already offer a powerful, carbon-free alternative to fossil fuels.

Implications for China’s Sustainable Development

China’s push toward cleaner energy and sustainable transport aligns perfectly with this breakthrough. Hydrogen combustion systems could play a pivotal role in replacing traditional diesel engines in sectors like agriculture, transportation, and industry, where zero-emission battery-electric options may not be practical. The ability to reduce NOx emissions cheaply and effectively addresses both environmental and public health concerns, contributing to efforts to tackle smog, fine particulate pollution, and ozone levels—all critical issues in many Chinese cities.

Fudong Liu, the lead researcher and associate professor of chemical and environmental engineering at UCR, explained, “Our findings show that hydrogen combustion can be made much cleaner, with applications ranging from trucks to backup generators. This technology offers a sustainable solution for industries that can’t easily transition to battery-electric systems.”

With governments and industries increasingly embracing hydrogen technologies, innovations like this could accelerate the shift toward a carbon-neutral future while minimizing air pollution risks. By addressing one of the key drawbacks of hydrogen ICEs, the research opens new opportunities for cleaner transportation and industrial applications, paving the way for hydrogen-powered systems to play a major role in China’s green transition.

Water-Rich Environment Boosts Catalyst Performance

The novel system capitalizes on the synergy between platinum and Y zeolite. Although Y zeolite itself isn’t a catalyst, it enhances the performance of platinum by capturing water generated during the hydrogen combustion process. This water-rich environment promotes hydrogen activation, a critical step in improving the reduction of NOx emissions.

Shaohua Xie, a research scientist at UCR and lead author of the study, emphasized the simplicity of the process:

“We just mix the two materials—platinum and zeolite—together, run the reaction, and see the improvement in activity and selectivity.”

The approach requires no complicated chemical processes, making it both cost-effective and easy to implement. Liping Liu, a PhD student at UCR, and Hongliang Xin, an associate professor at Virginia Tech, further validated the system’s effectiveness using theoretical modeling, reinforcing the practicality of the method.

Collaboration with BASF and Brookhaven National Laboratory

To test the catalytic system in real-world applications, UCR scientists prepared a powder mixture of platinum and Y zeolite and sent it to Yuejin Li at BASF Environmental Catalyst and Metal Solutions (ECMS). At BASF, the powder was transformed into a thick slurry, which was then coated onto honeycomb structures inside prototype catalytic converters. This prototype was developed in collaboration with scientists at the National Synchrotron Light Source II (NSLS-II) at Brookhaven National Laboratory, enabling precise testing and analysis.

With BASF funding the study and a pending patent in place, the researchers expect the technology to move swiftly toward commercialization.

“We are proud,” said Xie. “We’ve developed a new technology to control nitrogen oxide emissions, and we think it’s an amazing technique.”

Xie also noted that the concept is versatile:

“This concept can apply to other types of zeolites—it’s a universal strategy.”

Potential Impact for China’s Clean Energy Push

This breakthrough could be a game-changer for China’s hydrogen and diesel engines, offering a straightforward solution to a persistent problem: reducing NOx emissions. With hydrogen engines gaining momentum as a low-emission alternative to conventional diesel, this catalytic system aligns with China’s drive toward cleaner transportation and stricter pollution control standards.

The simplicity of the method makes it particularly appealing for rapid deployment across industries, including public transportation, heavy-duty trucks, and backup power generators. The water-capturing ability of the Y zeolite-enhanced platinum system ensures that emissions are reduced even during engine start-ups when catalytic converters typically operate less efficiently.

A Universal Strategy for Global Adoption

As China seeks innovative, cost-effective solutions to meet its 2030 peak emissions and 2060 carbon neutrality goals, this new catalytic system offers a promising pathway. Its scalability and versatility mean it can be applied not only to hydrogen engines but also to other zeolite-based systems, broadening its potential impact.

With commercialization on the horizon, this research exemplifies how straightforward yet powerful engineering solutions can play a crucial role in reducing pollution and improving air quality. UCR’s collaboration with BASF and Brookhaven demonstrates the value of cross-disciplinary partnerships in driving sustainable innovation.

This development provides a timely and practical solution for China’s clean energy ambitions—showing that simple ideas, when executed well, can have a profound environmental impact.